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Mechanistic Studies on Fast Ligand Substitution Reactions of Pt(II) in Different Ionic Liquids: Role of Solvent Polarity and Ion-Pair Formation

✍ Scribed by Begel, Svetlana; Illner, Peter; Kern, Simon; Puchta, Ralph; van Eldik, Rudi

Book ID
127103459
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
955 KB
Volume
47
Category
Article
ISSN
0020-1669

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Mechanistic Studies on Fast Ligand-Subst
Mechanistic Studies on Fast Ligand-Substitution Reactions of a Very Labile PdII Complex in Several Ionic Liquids
✍ Simon Kern; Peter Illner; Svetlana Begel; Rudi van Eldik 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 692 KB

## Abstract Detailed kinetic studies on the ligand‐substitution reactions of the very labile [Pd(terpy)Cl]^+^ (terpy = 2,2′:6′,2″‐terpyridine) complex have been performed for neutral and anionic nucleophiles in several imidazolium‐based ionic liquids. The detailed substitution mechanisms derived fr