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Mechanistic Studies of the Zirconium−Triisopropanolamine-Catalyzed Enantioselective Addition of Azide to Cyclohexene Oxide †

✍ Scribed by McCleland, Brent W.; Nugent, William A.; Finn, M. G.

Book ID
126058032
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
321 KB
Volume
63
Category
Article
ISSN
0022-3263

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## Abstract Nickel‐catalyzed addition of alkenylzirconium species to cyclopropyl ketones proceeds by an electron transfer mechanism. One‐electron reduction of the substrate leads to a ketyl which may either couple to give the 1, 2‐addition product or undergo a second one‐electron reduction, followe