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Mechanistic studies of the photorearrangement of o-nitrobenzyl esters

✍ Scribed by H. Schupp; W.K. Wong; W. Schnabel

Book ID
103491604
Publisher
Elsevier Science
Year
1987
Weight
599 KB
Volume
36
Category
Article
ISSN
0047-2670

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New o-, m-and p-nitrobenzyl esters of lasalocid (o-ELAS, m-ELAS and p-ELAS) have been synthesised and studied by X-ray, 1 H, 13 C NMR, FT-IR, UV-Vis, fluorescence as well as PM5 semiempirical methods. The crystal structure of o-ELAS is stabilized by three intramolecular hydrogen bonds in which the k