~SN CIDNP effects observed during nitration of phenolic compounds with nitric and nitrous acid are comparable showing that nitrous acid is not only a catalyst during nitration with nitric acid but also a reactive intermediate. The ~SN CIDNP effects are generated in radical pairs formed during encoun
✦ LIBER ✦
Mechanistic studies of the photochemical nitration of phenols, 1,2-dimethoxybenzene and anisoles with tetranitromethane by15N CIDNP
✍ Scribed by K. Schürmann; M. Lehnig
- Publisher
- Springer Vienna
- Year
- 2000
- Tongue
- English
- Weight
- 548 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0937-9347
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## Abstract The ^1^H, ^13^C and ^15^N NMR studies have shown that the __E__ and __Z__ isomers of pyrrole‐2‐carbaldehyde oxime adopt preferable conformation with the __syn__ orientation of the oxime group with respect to the pyrrole ring. The __syn__ conformation of __E__ and __Z__ isomers of pyrrol