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Mechanistic Studies of the Oxidative N -Dealkylation of a Substrate Tethered to Carboxylate-Bridged Diiron(II) Complexes, [Fe 2 (μ-O 2 CAr Tol ) 2 (O 2 CAr Tol ) 2 ( N,N -Bn 2 en) 2 ]

✍ Scribed by Yoon, Sungho; Lippard, Stephen J.

Book ID: 126975972
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 301 KB
Volume: 45
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic060307k

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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (