Mechanistic studies of the decomposition of dihalonitrobenzene anion radicals
β Scribed by James G. Lawless; M. Dale Hawley
- Publisher
- Elsevier Science
- Year
- 1969
- Weight
- 251 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0022-0728
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Recent chemical, electrochemical and electron spin resonance studies of halogenated nitroaromatics have shown that loss of anionic substituents is a frequently observed pathway for anion radical decomposition 1 -14. The neutral radicals which result from loss of the anionic substituents react by num
Mechanistic studies on the novel 7-endo selective radical cyclization were carried out. The reaction afforded three products, 7-endo product, 6-exo product, and reduced product. The distribution of these products was estimated by GC analyses. The 7-endo/6-exo selectivity was almost constant against