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Mechanistic Studies of Proton-Donor Coordination to Samarium Diiodide

✍ Scribed by Joseph A. Teprovich Jr.; Marielle N. Balili; Tomislav Pintauer; Robert A. Flowers II

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
418 KB
Volume
119
Category
Article
ISSN
0044-8249

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Studies on samarium diiodide initiated addition reaction of fluoroalkyl iodides to alkynes and its mechanism
✍ Shengming Ma; Xiyan Lu 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 423 KB

Abetract: Samarium diiodide was found to be an effective initiator in the addition reaction of fluoroalkyl iodides to alkynes. A single electrontransfer radical chain mechanism was proposed for the reaction based on ESR studies and other experimental results. Samarium diiodide, a strong single-elec