Mechanistic studies of oxidation of d-arabinose and d-mannose by acidic solution of N-bromoacetamide in presence of chloro-complex of Ru(III) as homogeneous catalyst
โ Scribed by Ashok Kumar Singh; Jaya Srivastava; Shahla Rahmani
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 384 KB
- Volume
- 271
- Category
- Article
- ISSN
- 1381-1169
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๐ SIMILAR VOLUMES
Kinetics of oxidation of diethylamine (DEA) by Bromamine-B (BAB) has been investigated at in acid solution with Ru(III) as catalyst. The oxidation behavior obeys 303 K the rate law, rate ฯญ k [BAB] [DEA] [Ru(III)] [H ฯฉ ] ฯชx where 'x' is less than unity indicating retardation of rate by [H ฯฉ ]. Added
The kinetics of oxidation of benzhydrol and its p-substituted derivatives (YBH, where Cl, Br, NO 2 , CH 3 , and OCH 3 ) by sodium N-chloro-p-toluenesulfonamide or chlor-Y ฯญ H, amine-T (CAT), catalyzed by ruthenium(III) chloride, in the presence of hydrochloric acid in 30% (v/v) MeOH medium has been