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Mechanistic studies of nineteen-electron organometallic complexes; synthesis of stable nineteen-electron complexes

✍ Scribed by David R. Tyler; Fei Mao


Book ID
113138437
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
921 KB
Volume
97
Category
Article
ISSN
0010-8545

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The mass spectra of several fluoroalkyl, fluoroalkenyl and fluoroacyl complexes of manganese, rhenium, iron and ruthenium carbonyls are described. After loss of carbonyl groups, fluoroalkyl compounds eliminate an olefin, with formation of metal halide species. A trifluorovinyl complex shows a novel