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Mechanistic studies and quantification of the electrophilicity of aromatic triflones in σ-complexation and SNAr reactions

✍ Scribed by ElGuesmi, Nizar; Berionni, Guillaume; Asghar, Basim H.

Book ID: 121506885
Publisher: Elsevier Science
Year: 2014
Tongue: English
Weight: 323 KB
Volume: 160
Category: Article
ISSN: 0022-1139
DOI: 10.1016/j.jfluchem.2014.01.003

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## Abstract Kinetic studies are reported for the reactions with aniline in benzene of a series of X‐phenyl 2,4,6‐trinitrophenyl ethers [X = H; 2‐, 3‐, 4‐CH~3~; 2,4‐, or 2,6‐(CH~3~)~2~] a–f, and the results compared with those of the corresponding nitro derivatives. In the methyl series, kinetic dat