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Mechanistic rationalization of an apparently non-stereospecific intramolecular Diels-Alder reaction

✍ Scribed by Philip Magnus; Clive Walker; Paul R. Jenkins; Keith A. Menear


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
204 KB
Volume
27
Category
Article
ISSN
0040-4039

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An intramolecular diels-alder reaction.
✍ L.H. Klemm; K.W. Gopinath πŸ“‚ Article πŸ“… 1963 πŸ› Elsevier Science 🌐 French βš– 135 KB

Y-AP~PICROP~D~PI~YLLIN (II) was isolated as a secondary degradation product resulting from dehydration of the naturally occurring, tumor-necrotizing compound podophyllotoxln. 1 II was found to be identical with a compound previously synthesized by Haworth and Richardson2 by a multiple-step procedure