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Mechanistic photochemistry of acylsilanes. 1. Reaction with alcohols

✍ Scribed by Bourque, Robert A.; Davis, Paul D.; Dalton, J. Christopher

Book ID
126062025
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
427 KB
Volume
103
Category
Article
ISSN
0002-7863

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## Abstract The Syntheses and the photolyses of the acylsilane **1** and the corresponding methyl ketone **2** are described. On n,Ο€\*‐excitation, the silyl ketone **1** as well as the methyl ketone **2** undergo a __Norrish__ type II reaction involving γ‐H‐abstraction and fragmentation to the dien