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Mechanistic Investigation of Uncatalyzed and Osmium(VIII) Catalyzed Oxidation of Guanidine by Ag(III) Periodate Complex in Aqueous Alkaline Medium: A Comparative Kinetic Approach

✍ Scribed by Abbar, Jyothi C.; Lamani, Shekappa D.; Nandibewoor, Sharanappa T.


Book ID
119976645
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
479 KB
Volume
48
Category
Article
ISSN
0888-5885

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✍ Jyothi C. Abbar; Shweta J. Malode; Sharanappa T. Nandibewoor πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 976 KB

The oxidation of dl-ornithine monohydrochloride (OMH) by diperiodatocuprate(III) (DPC) has been investigated both in the absence and presence of ruthenium(III) catalyst in aqueous alkaline medium at a constant ionic strength of 0.20 mol dm -3 spectrophotometrically. The stiochiometry was same in bot