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Mechanistic Investigation of Substrate Oxidation by Ce(IV) Reagents in Acetonitrile

✍ Scribed by Zhang, Yang; Flowers, Robert A.


Book ID
120825192
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
51 KB
Volume
68
Category
Article
ISSN
0022-3263

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Rate of oxidation of acetophenones by Ce(IV) in aqueous acetic acid 80: 20 ( v , ) either slows down or remains constant over a range of cetyltrimethyl ammonium bromide (CTAB) concentration exceeding the cmc value. The rate is then found to increase sharply as the surfactant concentration increases