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Mechanistic investigation of N-thioamidoimidates: Oxidation by heterogeneous and homogeneous electron transfers

✍ Scribed by Beya Haouas; Issa Tapsoba; Khaled Boujlel


Book ID
108119036
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
399 KB
Volume
52
Category
Article
ISSN
0013-4686

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Excess N-benzyl aziridine (1) reacts with I 2 to afford dimer 2, tetramer 3, benzaldehyde (4), and iodoamine 5. The reaction is interpreted as occurring by both electron transfer (ET) and heterolytic mechanisms. An ET mechanism is substantiated for the oxidation by I 2 of dimer 2 and tetramer 3, bot