## Abstract Activation of the SiB inter‐element bond with copper(I) alkoxides produces copper‐based silicon nucleophiles that react readily with aldehydes to yield α‐silyl alcohols (that is, α‐hydroxysilanes) after hydrolysis. Two independent protocols were developed, one employing a well‐defined
✦ LIBER ✦
Mechanistic Insights on the Stereoselective Nucleophilic 1,2-Addition to Sulfinyl Imines
✍ Scribed by Hennum, Martin; Fliegl, Heike; Gundersen, Lise-Lotte; Eisenstein, Odile
- Book ID
- 124060580
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 491 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Copper-Catalyzed 1,2-Addition of Nucleop
✍
Dr. Christian Kleeberg; Evgenia Feldmann; Eduard Hartmann; Devendra J. Vyas; Pro
📂
Article
📅
2011
🏛
John Wiley and Sons
🌐
English
⚖ 303 KB
Stereoselective Addition of 2-Phenyloxaz
✍
Morris, William J.; Muppalla, Kiran K.; Cowden, Cameron; Ball, Richard G.
📂
Article
📅
2012
🏛
American Chemical Society
🌐
English
⚖ 325 KB
Nucleophilic Attack on Coordinated Imine
✍
Thomas Birkle; Arancha Carbayo; José V. Cuevas; Gabriel García-Herbosa; Asunción
📂
Article
📅
2012
🏛
John Wiley and Sons
🌐
English
⚖ 703 KB
ChemInform Abstract: Stereoselective Syn
✍
Scott S. Harried; Michael D. Croghan; Matthew R. Kaller; Patricia Lopez; Wenge Z
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 52 KB
👁 2 views
Temperature and Solvent Effect on the Nu
✍
Prof. Dr. Gianfranco Cainelli; Dr. Daria Giacomini; Dr. Martin Walzl
📂
Article
📅
1995
🏛
John Wiley and Sons
🌐
English
⚖ 342 KB
👁 2 views
Are the Felkin–Ahn and Cram chelate models reliable? These models predict asymmetric induction without consideration of solvent and temperature. However, the addition of __n__‐butyllithium to the __N__‐(trimethylsily)imine of (2__S__)‐lactal leads to __syn/anti__ ratios between 98:2 and 28:72 when p
1,2-Addition of sulfur nucleophiles to t
✍
Clark, William M.; Swenton, John S.
📂
Article
📅
1990
🏛
American Chemical Society
🌐
English
⚖ 390 KB