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Mechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent

✍ Scribed by Collett, Christopher J.; Massey, Richard S.; Maguire, Oliver R.; Batsanov, Andrei S.; O'Donoghue, AnnMarie C.; Smith, Andrew D.


Book ID
118221174
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
749 KB
Volume
4
Category
Article
ISSN
2041-6520

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## Abstract A new PPh~3~‐catalyzed synthesis of alkyl 2‐[aryl(tosylimino)methyl]acrylates from propiolate and __N__‐tosylimine has been developed. Deuterium‐labelling experiments show that the reaction mechanism involves several hydrogen‐transfer processes, which are not the turnover‐limiting step