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Mechanistic Insights into the Stepwise Diels–Alder Reaction of 4,6-Dinitrobenzofuroxan

✍ Scribed by Linder, Mats; Johansson, Adam Johannes; Brinck, Tore


Book ID
127347165
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
749 KB
Volume
14
Category
Article
ISSN
1523-7060

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The Stepwise Diels–Alder Reaction of 4-N
✍ Dmitry V. Steglenko; Prof. Mikhail E. Kletsky; Prof. Sergey V. Kurbatov; Artem V 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 785 KB

## Abstract The Diels–Alder reaction of 4‐nitrobenzodifuroxan (NBDF) with 1‐methoxy‐3‐trimethylsilyloxy‐1,3‐butadiene has been investigated experimentally and theoretically. Treatment of NBDF with excess diene in chloroform at room temperature was found to afford a single product that contained a c