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Mechanistic Insight into the Cleavage of an Aromatic CC Bond by Tungsten

✍ Scribed by Dr. Jun Li; Prof. Dr. Kazunari Yoshizawa


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
281 KB
Volume
18
Category
Article
ISSN
0947-6539

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CCα Insertion: Insertion of an Alkyne in
✍ Seda Ünaldi; Rudolf Aumann; Roland Fröhlich 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB

## Abstract The first examples of insertion of a CC bond of an alkyne into a C~carbene~C~__α__~ single bond of a carbene complex (CC~__α__~ insertion) are reported. (__prim‐__Alkyl)carbene complexes [(OC)~5~MC(OEt)CH~2~R] (1 a–f; M=Cr, W; R=__n__Pr, C~7~H~7~, Ph) undergo CC~__α__~ insertion of