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Mechanistic details of the Belousov–Zhabotinsky oscillations. II. The organic reaction subset

✍ Scribed by D. Edelson; R. M. Noyes; R. J. Field

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
415 KB
Volume
11
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Our previous mechanistic model for the Belousov–Zhabotinsky reaction has been revised to include a more realistic set of reactions for the oxidation pathways of the organic intermediates. A few other rate constants have also been modified to include new information. The revised mechanism reproduces the essential experimental observations, although the periods of oscillation are somewhat too long and oscillations cease at malonic acid concentrations about ten times greater than the observed lower limit. However, the essential features of the mechanism are clearly understood.

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