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Mechanistic details of acid-catalyzed reactions and their role in the selective synthesis of triptane and isobutane from dimethyl ether

✍ Scribed by Dante A. Simonetti; John H. Ahn; Enrique Iglesia


Book ID
113686941
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
864 KB
Volume
277
Category
Article
ISSN
0021-9517

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## Abstract In this study, 13 different chiral 1,3‐diamines were synthesized from (−)‐__cis__‐2‐benzamidocyclohexanecarboxylic acid. They were successfully applied as ligands in the Cu‐catalyzed asymmetric Henry reaction between benzaldehyde and nitromethane. It was confirmed that the enantioselect