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Mechanistic Comparison of the Nickel(0)-Catalyzed Homo-Oligomerization and Co-Oligomerization of Alkynes and Nitriles

✍ Scribed by John J. Eisch; Xin Ma; Kyoung I. Han; John N. Gitua; Carl Krüger


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
502 KB
Volume
2001
Category
Article
ISSN
1434-1948

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✍ R.G. da Rosa; M.O. de Souza; R.F. de Souza 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 659 KB

This work describes cY-olefins oligomerization/co-oligomerization of I-butene, I-hexene, 1-octene to linear oligomers (Cs-C,, range) promoted by catalytic systems based on nickel(H) salts/alkylaluminum compounds. Conversion, selectivity (isomerization or oligomerization) and linearity are determined