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Mechanistic basis for rate enhancements in the methanolysis of aliphatic esters of quinine

✍ Scribed by Epperson, Matthew T.; Hadden, Chad E.; Waddell, Thomas G.


Book ID
115515427
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
255 KB
Volume
60
Category
Article
ISSN
0022-3263

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Palladium catalyzed activation of borane
✍ Michel Couturier; John L Tucker; Brian M Andresen; Pascal DubΓ©; Steven J Brenek; πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 71 KB

Hydrolytically stable borane-amines can be activated in situ through palladium catalysis and perform reductions not possible otherwise. Hence, borane-trimethylamine is an efficient hydrogen-transfer reagent for the open vessel reduction of nitroaryls to anilines. Likewise, the palladium catalyzed me