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Mechanistic aspects of vanadium catalysed oxidations with peroxides

✍ Scribed by Valeria Conte; Alessia Coletti; Barbara Floris; Giulia Licini; Cristiano Zonta


Book ID
108082489
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
982 KB
Volume
255
Category
Article
ISSN
0010-8545

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The thallimetric oxidation of carboxylic acids appears to proceed through free radical and intermediate activated complex mechanisms. The thermal and photochemical uncatalysed oxidation reactions appear to proceed through the formation of an intermediate metal-substrate complex that eventually decom