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Mechanistic aspects of the substrate ionization step in aminium salt catalyzed cyclopropanation

โœ Scribed by W. Yueh; N. L. Bauld


Book ID
111759990
Publisher
Springer Netherlands
Year
1997
Tongue
English
Weight
717 KB
Volume
23
Category
Article
ISSN
0922-6168

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Mechanistic aspects of aminium salt-cata
โœ Wang Yueh; Nathan L. Bauld ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 635 KB

Substituent effects in the aminium salt catalyzed Diels-Alder reactions of 2,3-dimethyl-l,3-butadiene with a series of metu and pam substituted /3-methylstyrenes are used to probe detailed mechanistic aspects of these reactions. Kinetic studies were carried out using two different aminium salt catal