Fluoride ion catalyzed reduction of aldehydes and ketones with hydrosilane in HMPA is found to involve a hexavalent silicate [HSiR3F(HMPA)]-as the active hydride species. and no evidence is obtained for interaction of the carbonyl oxygen with the silicon.
โฆ LIBER โฆ
Mechanistic aspects of the reduction of ruthenium(III) catalyzed
โ Scribed by Mallikarjuna I. Hiremath; Sharanappa T. Nandibewoor
- Book ID
- 106546899
- Publisher
- Springer
- Year
- 2004
- Tongue
- English
- Weight
- 122 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0340-4285
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