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Mechanistic Aspects of the Copolymerization Reaction of Carbon Dioxide and Epoxides, Using a Chiral Salen Chromium Chloride Catalyst

✍ Scribed by Darensbourg, Donald J.; Yarbrough, Jason C.


Book ID
126193215
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
141 KB
Volume
124
Category
Article
ISSN
0002-7863

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## Abstract The cobalt‐catalyzed alternating copolymerization of epoxides and CO is a novel, direct approach to aliphatic polyesters, such as poly(hydroxybutyrate) (PHB). This reaction was found to be catalyzed by Ph~3~Si[Co(CO)~4~] (4) and pyridine affording in a first step the stable mono‐inserti