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Mechanistic aspects of ligand substitution on [(H2O)(tap)2RuORu(tap)2(H2O)]2 + {tap=2-(m-tolylazo)pyridine} ion by three glycine-containing dipeptides in aqueous medium at physiological pH

✍ Scribed by ARUP MANDAL, SUBALA MONDAL, PARNAJYOTI KARMAKAR, BIPLAB K BERA, SUBHASIS MALLICK, ALAK K GHOSH

Book ID: 113094191
Publisher: Indian Academy of Sciences,Royal Society of Chemistry
Year: 2012
Tongue: English
Weight: 274 KB
Volume: 124
Category: Article
ISSN: 0253-4134
DOI: 10.1007/s12039-012-0245-1

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Mechanistic aspects of ligand substituti

Mechanistic aspects of ligand substitution on [(H2O)(tap)2RuORu(tap)2(H2O)]2+ ion {tap = 2-(m-tolylazo)pyridine} by some amino acids in aqueous medium at physiological pH

✍ Arup Mandal; Subala Mondal; Parnajyoti Karmakar; Subhasis Mallick; Biplab K. Ber 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 526 KB

## Abstract The interaction of the title complex with selected amino acids such as glycine (L^1^H), l‐valine (L^2^H), and l‐leucine (L^3^H) has been studied spectrophotometrically in aqueous medium as a function of [substrate complex], [ligand], and temperature. The reaction has been monitored at 6