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Mechanistic aspects in propene polymerization using mgcl2-supported ziegler-natta catalysts: behaviour of silane as an external lewis base

✍ Scribed by Roger Spitz; Charles Bobichon; Marie-France Llauro-Darricades; Alain Guyot; Laurent Duranel

Publisher
Elsevier Science
Year
1989
Weight
1005 KB
Volume
56
Category
Article
ISSN
0304-5102

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Use of different alkoxysilanes as extern
Use of different alkoxysilanes as external donors in MgCl2-supported Ziegler-Natta catalysts to obtain propene/1-butene copolymers with different microstructure
✍ Maria Carmela Sacchi; Zhi-Qiang Fan; Fabrizio Forlini; Incoronata Tritto; Paolo 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 757 KB

## Abstract The effects of different alkoxysilane donors (Ph(EtO)~3~Si, Me(EtO)~3~Si and Ph~2~(EtO)~2~Si) have been compared in propene/1‐butene copolymerization with MgCl~2~‐supported Ziegler‐Natta catalysts. The copolymers obtained were fractionated and the fractions characterized by ^13^C NMR an