The kinetics of oxidation of sulfanilic acid (p-aminobenzenesulfonic acid) by hexacyanoferrate(III) in alkaline medium was studied spectrophotometrically. The reaction showed first order kinetics in hexacyanoferrate(III) and alkali concentrations and an order of less than unity in sulfanilic acid co
Mechanistic and Spectral Studies of the Ruthenium(III) Catalysed Oxidation of Sulfanilic Acid by Alkaline Hexacyanoferrate(III)
β Scribed by Rahamatalla M. Mulla; Gurubasavaraj C. Hiremath; Sharanappa T. Nandibewoor
- Publisher
- Springer Vienna
- Year
- 2004
- Tongue
- English
- Weight
- 237 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0026-9247
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## Abstract The kinetics of Ruthenium (III) catalysed oxidation of LβValine by alkaline solution of hexacyanoferrate (III) were studied by following the rate of disappearance of Fe(CN)^3β^. The reaction shows zero order dependence on hexacyanoferrate (III). First order on ruthenium (III). The first
The kinetics of oxidation of six para-substituted diphenylmethanols (Y-DPM, where Y = H, Cl, Br, NO 2 , CH 3 and OCH 3 ) by sodium N-chlorobenzenesulphonamide [chloramine-B (CAB)] in the presence of HCl and catalysed by RuCl 3 in 30% (v/v) methanol medium was studied at 35 Β°C. The experimental rate