Extension of the reaction whereby "nucleoside dialdehydes" are cyclized by nitromethane [1,21 to nitromethane homologues [31 would be expected to produce branched nucleosides of pharmacological interest. 2-U-[(R)-Formyl-(1uracilyl)methyl] -( R )glyceraldehyde ("uridine dialdehyde") ( I ) , obtained
β¦ LIBER β¦
Mechanistic and Preparative Aspects of Vinyl Cation Chemistry
β Scribed by Prof. Dr. Michael Hanack
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 863 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract A >Pο£ΏO^β^ (**1**) type of anion has been used as an efficient synthetic precursor of fourβcoordinated compounds: R~2~P(O)ο£ΏHgο£Ώ(O)PR~2~ (**5**) and R~2~P(O)ο£ΏHgο£ΏBz (**3**) (R = alkoxy, alkyl, aryl). They were obtained in good yield. Bis(__t__βbutylβphenylphosphinitoβP)mercury (meso and rac