Mechanistic and kinetic study the reaction of O(3P)
β Scribed by Yunju Zhang; Jingyu Sun; Kai Chao; Hao Sun; Fang Wang; ShuWei Tang; Xiumei Pan; Jingping Zhang; Rongshun Wang
- Book ID
- 113021708
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 1001 KB
- Volume
- 131
- Category
- Article
- ISSN
- 1432-2234
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## Abstract The absolute rate constant of the reaction of O(^3^__P__) with toluene was measured by the microwave dischargeβfastβflow method to obtain __k__~__T__~ = 10^9.7β2.7/2.303__RT__^ l./moleΒ·sec at 100β375Β°C. This was in good agreement with the rate constant calculated from the combination of
A laser flash photolysis-resonance fluorescence technique has been employed to investigate the kinetics and mechanism of the reaction of electronically excited oxygen atoms, O( 1 D), with CF 2 HBr. Absolute rate coefficients (k 1 ) for the deactivation of O( 1 D) by CF 2 HBr have been measured as a