Mechanistic and kinetic studies on the polymerization of styrene initiated by dimethyl sulfonium 2-pyridyl carbonyl methylide

Atom transfer radical polymerization of

Atom transfer radical polymerization of styrene initiated by polychloroalkanes and catalyzed by CuCl/2,2′-bipyridine: A kinetic and mechanistic study

✍ Mathias Destarac; Jean-Marie Bessiere; Bernard Boutevin 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 281 KB 👁 2 views

A series of polychloroalkanes, known as telogen agents for redox telomerization, were used as initiators for atom transfer radical polymerization (ATRP) of styrene using the heterogeneous CuCl/2,2Ј-bipyridine catalyst. In copper-catalyzed redox telomerization, the reactivity of RCCl 3 -type telogens