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Mechanisms of thermal rearrangements of bicyclo[3.2.1]Octa-2,6-dienes; steric effects as a tool to distinguish between competing pericyclic and diradical processes

✍ Scribed by J. Japenga; G.W. Klumpp; M. Schakel


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
189 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis


In order to gain some insight into the mechanisms of the thermal transformations

I+11

and I-III1 the rearrangements of several substituted bicyclo[3.2.1]acts-2,6-dienes were studied. Results are given in Table 1.