Mechanisms of propagation, transfer, and short-chain branching reactions in the free-radical polymerization of ethylene
β Scribed by Machi, Sueo ;Kise, Seiichi ;Hagiwara, Miyuki ;Kagiya, Tsutomu
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1967
- Tongue
- English
- Weight
- 580 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0449-296X
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π SIMILAR VOLUMES
## M - w vs conversion for several experiments. Also shown are linear fits to the asymptotically linear portion described by the QSSA.
The role of monomer in catalytic chain transfer polymerization was studied by determination of the chain transfer constants of the tetraphenyl derivative of cobaloxime boron fluoride (COPhBF) in methyl methacrylate at 60 8C varying the monomer concentration instead of the COPhBF concentration as is
## Abstract Chain transfer to polymer (CTP) in conventional freeβradical polymerizations (FRPs) and controlled radical polymerizations (ATRP, RAFT and NMP) of __n__βbutyl acrylate (BA) has been investigated using ^13^C NMR measurements of branching in the poly(__n__βbutyl acrylate) produced. The mo