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Mechanisms of photochemical reactions in solution. 80. Photochemical oxidation of tris(2,2'-bipyridyl)ruthenium(II) by molecular oxygen

โœ Scribed by Winterle, John S.; Kliger, David S.; Hammond, George S.


Book ID
127311597
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
381 KB
Volume
98
Category
Article
ISSN
0002-7863

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## Abstract Excitation of Ru(bipy)~3~^2+^ ion by visible radiation of wavelength ฮป = 436 nm in aqueous medium in presence of inorganic peroxides, peroxomonosulfate (PMS), peroxodisulfate (PDS), and peroxodiphosphate (PDP) was found to generate Ru(bipy)~3~^3+^. The kinetics of this photochemical oxi