✦ LIBER ✦
Mechanisms of mass spectrometric fragmentations: X–Interaction between remote or-groups in decalin-1,5-diols and their dimethyl ethers
✍ Scribed by Hans-Friedrich Grützmacher; Karl-Heinz Fechner
- Book ID
- 102557078
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 199 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
Abstract
The mass spectra of the five stereoisomers of decalin‐1,5‐diol and its dimethyl ether have been investigated. The differences in the mass spectra of stereoisomers I to III with a trans‐ decalin ting system are small. The differences are much larger in the mass spectra of the two isomers IV and V of the cis‐decalin series and the elimination of CH~2~O, formed by interaction between the two methoxy groups, from the molecular ion is only observed in the mass spectrum of Vb.