Mechanisms of ion-molecule reactions of propene and cyclopropane
β Scribed by Bowers, Michael T.; Aue, Donald H.; Elleman, Daniel D.
- Book ID
- 126909392
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 807 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The gas-phase reactions of propene and cyclopropane radical cations with neutral ethylene were investigated by using Fourier transform, chemical ionization and tandem mass spectrometries. Both reactions form covalent C,H,, adduct ions. The adduct ions are hypothesized to form initially as distonic r
By ion cyclotron resonance it is found that various substituted cyclopropanes after ionization react with ammonia to give products which allow identification of the degree and kind of substitution on the cyclopropyl ring. For example, cyclopropane reacts to give[CH2NH,]+ (m/e 30), methylcyclopropane