Some recent studies of inner-sphere and outer-sphere electron-transfer reactions in solution are described. Various indirect criteria for determining the mechanisms of electron-transfer re actions and the question of ligand bridging at electrodes are discussed.
Mechanisms of Glycopyranosyl and 5-Thioglycopyranosyl Transfer Reactions in Solution.
β Scribed by Andrew J. Bennet; Theresa E. Kitos
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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The kinetics and mechanisms of the reactions of aluminium(III) with pentane-2,4dione (Hpd), 1,1,1-trifluoro pentane-2,4-dione (Htfpd) and heptane-3,5-dione (Hhptd) have been investigated in aqueous solution at and ionic strength sodium per-Οͺ3 25ΠC 0.5 mol dm chlorate. The kinetic data are consistent