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Mechanisms of Franck–Condon breakdown over a broad energy range in the valence photoionization of N2 and CO

✍ Scribed by J.A. López-Domínguez; David Hardy; Aloke Das; E.D. Poliakoff; Alex Aguilar; Robert R. Lucchese


Book ID
119235552
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
713 KB
Volume
185
Category
Article
ISSN
0368-2048

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The photoelectron spectrum of gaseous COz is investigated in the inner valence electron region, between 20 and 45 eV binding energies for photon energies between 40 and 100 eV using synchrotron radiation. The branching ratio for inner valence ionizations increases considerably as a function of photo