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Mechanisms of elimination reactions. 29. Deuterium kinetic isotope effects in eliminations from amine oxides. The consequences of nonlinear proton transfer

โœ Scribed by Chiao, Wen-Bin; Saunders, William H.


Book ID
126444651
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
475 KB
Volume
100
Category
Article
ISSN
0002-7863

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โœ Kurt W. Egger ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')