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Mechanisms of electrophilic substitution in metallocenes: The inside-outside relationship

✍ Scribed by John A. Mangravite; T.G. Traylor

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 281 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89534-4

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✦ Synopsis

A popular mechanism for electrophilic substitution in metallocenes is one in which ring substitution occurs through rate-limiting transfer of electrophile from a metal-

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We picture the role of the metal,complexed cation (I) (if it exists) as being the counterpart of the v-complex in bensenoid substitution and have excluded it from our scheme.

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