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Mechanisms of antioxidant action: rubber bound antioxidants based on nitrones—I. Non-sulphur vulcanizates

✍ Scribed by G. Scott; K.V. Smith


Book ID
107753560
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
476 KB
Volume
14
Category
Article
ISSN
0014-3057

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✍ K.W.S. Kularatne; G. Scott 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 360 KB

The mechanism of by-product formation in the reaction of a thiol antioxidant, 3,5-di-tertbutyl-4-hydroxybenzyl mercaptan (BHBM), with rubber latices is shown to involve two processes, viz dimerization of the intermediate thiyl radical to give disulphide (BHBDS) and the reaction of the intermediate q