The tetrakis (dialkyldithiocarbamato)tellurium(Iv) complexes are highly effective thermal antioxidants and melt stabilizers for polypropylene and the evidence suggests that they are converted to the bis(dialkyldithiocarbamato)tellurium(II) complexes and the corresponding dithiocarbamoyl disulfides d
Mechanisms of antioxidant action: Phenolic sulphides as antidegradants for rubbers
β Scribed by A. Ogunbanjo; G. Scott
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 314 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0014-3057
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β¦ Synopsis
lt is shown that autosynergistic phenolic sulphides are effective non-discolouring antidegradants for vulcanised natural rubber. They are in general more effective in non-sulphur vulcanisates (peroxide and thiuram) than in the conventional polysulphide rubbers. There is evidence that the processing and vulcanisation operations may play some part in the transformation of the antidegradants to more active products.
π SIMILAR VOLUMES
Simple hindered phenols, containing ortho or para methyl groups, react with natural rubber latex in the presence of oxidizing free radicals (alkoxy or acyloxy), giving t,p to 20% yields of bound antioxidant. This reaction is most efficient when the concentration of the phenolic antioxidant in the ru