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Mechanisms and Products of Surface-Mediated Reductive Dehalogenation of Carbon Tetrachloride by Fe(II) on Goethite

✍ Scribed by Elsner, Martin; Haderlein, Stefan B.; Kellerhals, Thomas; Luzi, Samuel; Zwank, Luc; Angst, Werner; Schwarzenbach, René P.


Book ID
120272140
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
192 KB
Volume
38
Category
Article
ISSN
0013-936X

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## Abstract The kinetics of the H~2~O~2~ decomposition by Cu(II)‐, Co(II)‐, and Fe(III)‐amine complexes supported on the surface of silica‐alumina (25% Al~2~O~3~) catalyst have been investigated. The decomposition process proceeded with first‐order kinetics for the substrate concentration. With cop