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Mechanism of thietane formation from the reaction of 1,3-dioxan-2-ones with thiocyanate ion. Stereochemical investigation

✍ Scribed by Paquette, Leo A.; Freeman, John P.


Book ID
121382096
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
729 KB
Volume
35
Category
Article
ISSN
0022-3263

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Reaction of 2-ammosugars with isocyanates has been extended to other higher-carbon sugars. Ureido derivat~es or, in most cams. monocychc struc~es can be easily isolated Importantly, the last substances display a relative rrons disposition between the substituents at C-4 and C-5 of the heterocyclic r