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Mechanism of thermal generation of poly(p-phenylene vinylene) from poly(p-xylene-α-dimethylsulphonium halides)

✍ Scribed by G. Montaudo; D. Vitalini; R.W. Lenz

Book ID: 107844939
Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 482 KB
Volume: 28
Category: Article
ISSN: 0032-3861
DOI: 10.1016/0032-3861(87)90237-0

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This paper reports the thermal conversion of the tetrahydrothiophene (THT)-precursor to poly(p-phenylene vinylene) (PPV). Detailed investigations of the conversion process show that the leaving groups THT and HCl do not eliminate simultaneously. Moderate temperatures ( 125 °C) are sufficient to elim