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Mechanism of the Ta + -Mediated Activation of the C−H Bond in Methane

✍ Scribed by Sändig, Nadja; Koch, Wolfram

Book ID
127170397
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
250 KB
Volume
16
Category
Article
ISSN
0276-7333

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✍ Yuri A. Gruzdkov; Kazuo Watanabe; Kyoichi Sawabe; Yoshiyasu Matsumoto 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 449 KB

Methane adsorbed on a Pt ( 111) surface simply desorbs at x 70 K. However, after the methane-precovered surface is irradiated with 193 nm photons, the intensity of the thermal desorption peak decreases and a new peak of methane at w 260 K grows with the accumulated number of photons. This new desorp