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Mechanism of the Rhodium-Catalyzed Asymmetric Isomerization of Allylamines to Enamines

✍ Scribed by Ainara Nova; Gregori Ujaque; Ana C. Albéniz; Pablo Espinet

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
581 KB
Volume
14
Category
Article
ISSN
0947-6539

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Bis[(R)-(+)-binap]rhodium(I) Perchlorate
Bis[(R)-(+)-binap]rhodium(I) Perchlorate, a Highly Efficient Catalyst for the Asymmetric Isomerization of Allylamines
✍ Dr. Kazuhide Tani; Dr. Tsuneaki Yamagata; Dr. Yoshitaka Tatsuno; Dr. Yuriko Yama 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB 👁 1 views

activation entropy and the minimal influence of solvent rule out an ionic mechanism. The reaction Id + 2b could proceed via bicyclic triazoIines["' or be interpreted as a hetero-Cope rearrangement'"'. Table I. Some physical data of the new compounds Id, 2b, 4a, 5, 6a, and 6b.