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Mechanism of the reductive dehalogenation of gem-dihalocyclopropane

✍ Scribed by A. I. D'yachenko; T. Yu. Rudashevskaya; O. S. Korneva; A. Ya. Shteinshneider; O. M. Nefedov

Book ID
112440113
Publisher
Springer
Year
1978
Tongue
English
Weight
73 KB
Volume
27
Category
Article
ISSN
1573-9171

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The method described by Makosza and Wawrzyniewicz 1,2,3 is a most useful addition to the arsenal of dihalocarbene-generating reactions4. The two-phase reaction system consisting of the olefins, chloroform, and 50% aqueous sodium hydroxide with a tetraalkylammonium chloride as catalyst provides a par